Ultrahigh-Energy-Density Sorption Thermal Battery Enabled by Graphene Aerogel-Based Composite Sorbents for Thermal Energy Harvesting from Air
نویسندگان
چکیده
Sorption-based thermal storage has drawn considerable attention for sustainable and cost-effective management energy storage. However, the low sorption capacity of sorbents is a long-standing challenge achieving high-energy-density sorption-based Herein, we demonstrate an ultrahigh-energy/power-density battery (STB) enabled by graphene aerogel (GA)-based composite efficient harvesting with record performance. Scalable GA-based high salt loading are synthesized confined calcium chloride inside GA matrix (CaCl2@GA), showing fast kinetics large up to 2.89 g·g-1 contributed chemisorption-deliquescence-absorption CaCl2. The STB realizes charging-discharging via multistep water desorption-sorption CaCl2@GA sorbent humidity from air. Importantly, lab-scale exhibits density 1580 Wh·kg-1 power 815 W·kg-1 space heating. Our work offers promising low-carbon route harvesting, storage, utilization. ©
منابع مشابه
Membrane-free battery for harvesting low-grade thermal energy.
Efficient and low-cost systems are desired to harvest the tremendous amount of energy stored in low-grade heat sources (<100 °C). An attractive approach is the thermally regenerative electrochemical cycle (TREC), which uses the dependence of electrode potential on temperature to construct a thermodynamic cycle for direct heat-to-electricity conversion. By varying the temperature, an electrochem...
متن کامل“Solar and Thermal Energy Harvesting Textile Composites
Form Approved OMB No. 0704-0188 Public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing this collection of information. Send comments regarding this burden estimate or any other aspect of this coll...
متن کاملGraphene-based photovoltaic cells for near-field thermal energy conversion
Thermophotovoltaic devices are energy-conversion systems generating an electric current from the thermal photons radiated by a hot body. While their efficiency is limited in far field by the Schockley-Queisser limit, in near field the heat flux transferred to a photovoltaic cell can be largely enhanced because of the contribution of evanescent photons, in particular for a source supporting a su...
متن کاملGraphene/elastomer composite-based photo-thermal nanopositioners
The addition of nanomaterials to polymers can result not only in significant material property improvements, but also assist in creating entirely new composite functionalities. By dispersing graphene nanoplatelets (GNPs) within a polydimethylsiloxane matrix, we show that efficient light absorption by GNPs and subsequent energy transduction to the polymeric chains can be used to controllably pro...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ACS energy letters
سال: 2021
ISSN: ['2380-8195']
DOI: https://doi.org/10.1021/acsenergylett.1c00284